OREAS 935
SKU: 935
OREAS 935 is one of a suite of sixteen copper ore CRMs (OREAS 920 to OREAS
935) prepared from material from the CSA mine located near the town of Cobar in
central western New South Wales, Australia. The copper ore body is hosted by the
Early Devonian CSA Siltstone, a thinly bedded turbiditic sequence of
carbonaceous siltstones and mudstones with minor coarser units. The CSA
Siltstone is part of the Cobar Supergroup, consisting of lower syn-rift
sediments and upper post-rift sag phase sediments. The mineralisation is
structurally controlled and confined to a number of steeply dipping bodies
within a major shear zone on the eastern margin of the Early Devonian Cobar
Basin. It is characterised by low-grade greenschist alteration and epigenetic
low-grade mineralisation enveloping higher-grade shoots of vein complexes or
sub-massive to massive sulphides. The sulphides include chalcopyrite,
pyrrhotite, pyrite, sphalerite, galena, bornite and cubanite. Iron-rich chlorite
and silica are prominent alterations in the siltstone host.
Twenty two commercial analytical laboratories participated in the program to
characterise the analytes reported below. The following methods were employed
for method specific certification:
Four acid (HCl-HNO3-HF-HClO4) digestion with
ICP-OES, ICP-MS or AAS finish (21 laboratories);
Aqua regia digestion with ICP-OES, ICP-MS or AAS finish (20 laboratories);
Infrared combustion furnace for sulphur (19 laboratories);
Borate or pyro-sulphate fusion with XRF (12 laboratories);packaging in 10g
units sealed under nitrogen, in laminated foil pouches
Peroxide fusion with ICP-OES, ICP-MS or AAS finish (16
laboratories).
This CRM is packaged in 10g units sealed under nitrogen in laminated foil
pouches.
Specifications
- State: primary
- Matrix: siltstone
- Mineralisation: structurally-controlled sediment-hosted
- CRM Group: Cu ore
Certified Values
| Analyte | Certified Value | 1SD | 95% CL Low | 95% CL High | Method |
|---|---|---|---|---|---|
| Cu, Copper (wt.%) | 12.55 | 0.388 | 12.40 | 12.71 | 4-Acid Digestion |
| Ag, Silver (ppm) | 46.1 | 6.4 | 43.5 | 48.7 | 4-Acid Digestion |
| Zn, Zinc (ppm) | 692 | 51 | 670 | 715 | 4-Acid Digestion |
| Al, Aluminium (wt.%) | 3.55 | 0.50 | 2.78 | 4.32 | 4-Acid Digestion |
| As, Arsenic (ppm) | 8.72 | 1.10 | 8.32 | 9.12 | 4-Acid Digestion |
| Be, Beryllium (ppm) | < 2.00 | IND | IND | IND | 4-Acid Digestion |
| Bi, Bismuth (ppm) | 709 | 60 | 681 | 738 | 4-Acid Digestion |
| Ca, Calcium (wt.%) | 0.320 | 0.015 | 0.304 | 0.337 | 4-Acid Digestion |
| Cd, Cadmium (ppm) | < 2.00 | IND | IND | IND | 4-Acid Digestion |
| Co, Cobalt (ppm) | 77 | 4.1 | 75 | 79 | 4-Acid Digestion |
| Cr, Chromium (ppm) | 37.6 | 4.5 | 32.6 | 42.5 | 4-Acid Digestion |
| Fe, Iron (wt.%) | 22.89 | 1.607 | 22.06 | 23.71 | 4-Acid Digestion |
| La, Lanthanum (ppm) | 23.0 | 2.5 | 19.8 | 26.2 | 4-Acid Digestion |
| Li, Lithium (ppm) | 12.9 | 2.3 | 10.5 | 15.3 | 4-Acid Digestion |
| Mg, Magnesium (wt.%) | 0.802 | 0.055 | 0.750 | 0.855 | 4-Acid Digestion |
| Mn, Manganese (wt.%) | 0.070 | 0.004 | 0.066 | 0.074 | 4-Acid Digestion |
| Nb, Niobium (ppm) | 6.53 | 0.73 | 5.75 | 7.30 | 4-Acid Digestion |
| Ni, Nickel (ppm) | 29.7 | 3.3 | 27.2 | 32.3 | 4-Acid Digestion |
| P, Phosphorus (wt.%) | < 0.050 | IND | IND | IND | 4-Acid Digestion |
| Pb, Lead (ppm) | 225 | 22 | 215 | 236 | 4-Acid Digestion |
| S, Sulphur (wt.%) | 11.83 | 2.29 | 10.60 | 13.07 | 4-Acid Digestion |
| Sb, Antimony (ppm) | 2.70 | 0.38 | 2.49 | 2.92 | 4-Acid Digestion |
| Se, Selenium (ppm) | 88 | 15 | 80 | 95 | 4-Acid Digestion |
| Sn, Tin (ppm) | 108 | 7 | 104 | 111 | 4-Acid Digestion |
| Sr, Strontium (ppm) | 24.2 | 2.8 | 20.4 | 28.0 | 4-Acid Digestion |
| Th, Thorium (ppm) | 7.90 | 1.18 | 6.83 | 8.98 | 4-Acid Digestion |
| Ti, Titanium (wt.%) | 0.182 | 0.014 | 0.165 | 0.198 | 4-Acid Digestion |
| V, Vanadium (ppm) | < 60 | IND | IND | IND | 4-Acid Digestion |
| W, Tungsten (ppm) | 36.0 | 4.3 | 31.1 | 40.9 | 4-Acid Digestion |
| Y, Yttrium (ppm) | 12.3 | 1.3 | 11.0 | 13.6 | 4-Acid Digestion |
| Zr, Zirconium (ppm) | 47.4 | 5.5 | 40.6 | 54.2 | 4-Acid Digestion |
| Ag, Silver (ppm) | 43.7 | 5.4 | 41.2 | 46.1 | Aqua Regia Digestion |
| Al, Aluminium (wt.%) | 1.65 | 0.126 | 1.49 | 1.81 | Aqua Regia Digestion |
| As, Arsenic (ppm) | 8.77 | 1.59 | 8.04 | 9.49 | Aqua Regia Digestion |
| Bi, Bismuth (ppm) | 680 | 43 | 657 | 703 | Aqua Regia Digestion |
| Ca, Calcium (wt.%) | 0.240 | 0.012 | 0.230 | 0.249 | Aqua Regia Digestion |
| Co, Cobalt (ppm) | 77 | 4.4 | 74 | 79 | Aqua Regia Digestion |
| Cr, Chromium (ppm) | 20.4 | 1.15 | 19.0 | 21.7 | Aqua Regia Digestion |
| Cu, Copper (wt.%) | 12.48 | 0.413 | 12.26 | 12.71 | Aqua Regia Digestion |
| Fe, Iron (wt.%) | 22.76 | 1.619 | 21.82 | 23.70 | Aqua Regia Digestion |
| K, Potassium (wt.%) | 0.217 | 0.019 | 0.196 | 0.237 | Aqua Regia Digestion |
| Mg, Magnesium (wt.%) | 0.665 | 0.045 | 0.609 | 0.722 | Aqua Regia Digestion |
| Mn, Manganese (wt.%) | 0.064 | 0.006 | 0.058 | 0.071 | Aqua Regia Digestion |
| Mo, Molybdenum (ppm) | < 1.60 | IND | IND | IND | Aqua Regia Digestion |
| Na, Sodium (wt.%) | < 0.030 | IND | IND | IND | Aqua Regia Digestion |
| Ni, Nickel (ppm) | 26.2 | 2.8 | 22.8 | 29.5 | Aqua Regia Digestion |
| Pb, Lead (ppm) | 222 | 16 | 214 | 230 | Aqua Regia Digestion |
| Sb, Antimony (ppm) | < 2.00 | IND | IND | IND | Aqua Regia Digestion |
| Se, Selenium (ppm) | 86 | 10 | 81 | 92 | Aqua Regia Digestion |
| Sn, Tin (ppm) | 96 | 8.4 | 91 | 102 | Aqua Regia Digestion |
| Sr, Strontium (ppm) | 13.8 | 0.94 | 12.8 | 14.9 | Aqua Regia Digestion |
| Ti, Titanium (wt.%) | 0.041 | 0.007 | 0.032 | 0.051 | Aqua Regia Digestion |
| W, Tungsten (ppm) | 30.1 | 4.7 | 24.0 | 36.3 | Aqua Regia Digestion |
| Zn, Zinc (ppm) | 666 | 59 | 638 | 693 | Aqua Regia Digestion |
| S, Sulphur (wt.%) | 14.36 | 0.339 | 14.21 | 14.52 | Infrared Combustion |
| Co, Cobalt (ppm) | < 100 | IND | IND | IND | Borate Fusion XRF |
| Cu, Copper (wt.%) | 12.54 | 0.296 | 12.33 | 12.74 | Borate Fusion XRF |
| Fe2O3, Iron(III) oxide (wt.%) | 33.80 | 1.047 | 33.09 | 34.50 | Borate Fusion XRF |
| Pb, Lead (ppm) | 255 | 49 | 208 | 302 | Borate Fusion XRF |
| S, Sulphur (wt.%) | 14.60 | 0.383 | 14.12 | 15.07 | Borate Fusion XRF |
| SiO2, Silicon dioxide (wt.%) | 31.25 | 0.703 | 30.58 | 31.92 | Borate Fusion XRF |
| Zn, Zinc (ppm) | 688 | 37 | 664 | 712 | Borate Fusion XRF |
| Ag, Silver (ppm) | 43.7 | 4.10 | 40.9 | 46.6 | Peroxide Fusion ICP |
| As, Arsenic (ppm) | < 20.0 | IND | IND | IND | Peroxide Fusion ICP |
| Bi, Bismuth (ppm) | 679 | 28 | 663 | 695 | Peroxide Fusion ICP |
| Co, Cobalt (ppm) | 85 | 10 | 78 | 91 | Peroxide Fusion ICP |
| Cu, Copper (wt.%) | 12.43 | 0.370 | 12.23 | 12.63 | Peroxide Fusion ICP |
| Fe, Iron (wt.%) | 23.59 | 1.153 | 22.97 | 24.21 | Peroxide Fusion ICP |
| Pb, Lead (ppm) | 233 | 33 | 220 | 247 | Peroxide Fusion ICP |
| S, Sulphur (wt.%) | 14.59 | 0.340 | 14.39 | 14.79 | Peroxide Fusion ICP |
| Sb, Antimony (ppm) | 2.79 | 0.42 | 2.54 | 3.04 | Peroxide Fusion ICP |
| Se, Selenium (ppm) | 105 | 11 | 95 | 115 | Peroxide Fusion ICP |
| Si, Silicon (wt.%) | 14.75 | 0.271 | 14.56 | 14.95 | Peroxide Fusion ICP |
| Sn, Tin (ppm) | 119 | 9 | 113 | 126 | Peroxide Fusion ICP |
| Zn, Zinc (ppm) | 721 | 43 | 699 | 743 | Peroxide Fusion ICP |
Product Specifications
Certified Reference Values
| Analyte | Certified Value | Uncertainty (1SD) | 95% Confidence Low | 95% Confidence High | Method |
|---|---|---|---|---|---|
| La - Lanthanum (ppm) | 23.0 | - | - | - | 4-Acid Digestion |
| Y - Yttrium (ppm) | 12.3 | - | - | - | 4-Acid Digestion |
| Ag - Silver (ppm) | 43.7 | - | - | - | Aqua Regia |
| As - Arsenic (ppm) | 8.77 | - | - | - | Aqua Regia |
| Bi - Bismuth (ppm) | 680 | - | - | - | Aqua Regia |
| Co - Cobalt (ppm) | 77 | - | - | - | Aqua Regia |
| Ni - Nickel (ppm) | 26.2 | - | - | - | Aqua Regia |
| Pb - Lead (ppm) | 222 | - | - | - | Aqua Regia |
| Se - Selenium (ppm) | 86 | - | - | - | Aqua Regia |
| Sn - Tin (ppm) | 96 | - | - | - | Aqua Regia |
| Zn - Zinc (ppm) | 666 | - | - | - | Aqua Regia |
SD = Standard Deviation | CL = 95% Confidence Limits
Methods: AR = Aqua Regia, 4-Acid = 4-Acid Digestion, LBF = Lithium Borate Fusion, FA/AAS = Fire Assay with Atomic Absorption, LECO = LECO Combustion Analysis
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